Brangelina: the timeline
2004: Mr & Mrs Smith: The couple meet on the set of the film 'Mr & Mrs Smith', in which they have the lead roles. In the same year, Pitt files for divorce from his first wife Jennifer Aniston.
Jolie's first pregnancy
In early 2006, Jolie confirms that she is pregnant with Pitt's child - acknowledging the relationship publicly for the first time.
The couple found the Jolie-Pitt Foundation; a charity aimed at supporting international humanitarian causes.
Twins bring number of children to six
Jolie announces she is pregnant with twins in May 2008 at the Cannes Film Festival. She gives birth to a boy and a girl in July of that year, bringing the couple's total number of children to six including three adoptions, from Cambodia, Ethiopia and Vietnam.
August 23, 2014
Tie the knot
The couple get married at Chateau Miraval, their home in the south of France, more than two years after their engagement.
September 20, 2016
Jolie files for divorce
Jolie's lawyer confirms that the actress has filed for divorce. TMZ reports that she has asked for custody of the couple's six children, with visitation rights for Pitt.